
Sodium 2-Nitrophenolate
- Chemical Formula : C6H4NO3Na (sodium phenolate formula)
- CAS No : 824-39-5
- EC No : 212-527-5
- Purity by Bromination : Minimum 76% as Na-ONP (Anhydrous)
- Purity by Gas Chromatograph: Minimum 99.50%
- Moisture Content:Maximum 24.0% including water of crystallization
- Packaging: Packed in 50 kg HDPE woven bags with polyliner for protection
About the Product
Sodium 2-nitrophenolate, also called nitrophenolate sodium, is the sodium salt of 2-Nitrophenol. It is sometimes referred to as sodium ortho nitrophenolate because the nitro group (-NO₂) is at the ortho position relative to the hydroxyl group on the benzene ring. This compound combines the properties of phenol derivatives with sodium ions, resulting in enhanced solubility and reactivity.
- Appearance: Bright red crystalline solid
- Solubility: Highly soluble in water
- Structure: The structure of sodium phenate shows a benzene ring with a nitro group in ortho position and a phenolate (-O⁻) group attached to sodium (Na⁺).
This combination gives the compound both phenolic and ionic properties, making it versatile for multiple industrial applications.


Synthesis Methods
Sodium 2-nitrophenolate is synthesized mainly through the following methods:
- 1. Reaction with Sodium Hydroxide:2-Nitrophenol reacts with sodium hydroxide (NaOH) in aqueous solution, replacing the hydrogen atom of the hydroxyl group with sodium, forming sodium nitrophenolate.
- 2. Reaction with Ortho Nitro Chloro Benzene (ONCB):Another process involves reacting Ortho Nitro Chloro Benzene with NaOH under controlled temperature conditions to yield sodium ortho nitrophenolate.
Applications
1. Organic Synthesis
Sodium nitrophenolate serves as a key intermediate in organic synthesis.
- Used for making pharmaceuticals, dyes, and agrochemicals.
- Its phenolate group undergoes substitution reactions easily, allowing further functionalization.
2. Agricultural Sector
- Functions as a plant growth regulator and elicitor.
- Enhances seed germination, root growth, and flowering.
- Improves crop yield and resistance against pathogens.
- Its nitrophenolate sodium form provides bioavailability for plant absorption.
3. Pharmaceutical Industry
- Exhibits antimicrobial, antifungal, and anticancer properties.
- Used in the synthesis of drug intermediates and active pharmaceutical ingredients (APIs).
4. Dye and Pigment Industry
- Acts as an intermediate in the production of stable and vibrant dyes.
- mmonly used in textiles, inks, and coatings.


Packaging
- Acts as an intermediate in the production of stable and vibrant dyes.
- mmonly used in textiles, inks, and coatings.
Domestic
HDPE woven bags (50 kg) with LDPE liner; Fiber Drums (25 kg optional).
Export
UN Approved HDPE Drums or Bags (25 kg) with LDPE liner inside.
Differences Between Sodium 2-Nitrophenolate and Sodium 4-Nitrophenolate
Position of Nitro Group:
- In sodium ortho nitrophenolate, the nitro group is at the ortho position.
- In sodium 4-nitrophenolate, it is at the para position.
Structure and Reactivity:
The difference in the position leads to distinct reactivity and applications.

Conclusion
Sodium 2-nitrophenolate (NaONP) is an essential chemical for organic synthesis, agriculture, pharmaceuticals, and dyes. With its unique structure of sodium phenate and combined phenolic/ionic properties, it is a critical intermediate for modern industrial processes.
FAQs
Sodium nitrophenolate is the sodium salt of nitrophenol, widely used in organic synthesis, agriculture, and dyes.
Yes, both names refer to the same compound since the nitro group is at the ortho position on the benzene ring.
The sodium phenolate formula for this compound is C₆H₄NO₃Na.
The structure of sodium phenate includes a benzene ring with a hydroxyl group deprotonated (forming -O⁻) attached to sodium and a nitro group (-NO₂) in the ortho position.
It is used in pharmaceutical synthesis, plant growth regulation, dye production, and agrochemical formulations.
It acts as a plant growth stimulator, improving germination, root growth, and resistance to stress.
Yes, it is highly water-soluble, which makes it suitable for agricultural spraying and chemical processes.